Z Wave was designed as a RF-only protocol (vs. Insteon for example, which was designed to be RF and powerline), I have not ever seen a hard-wired Z Wave extender. I have seen discussions of people using a pair of Smartthings hubs on a Ethernet network to get the effect you are looking for, but I am not sure how well it would be to manage.
Given the way the Z Wave mesh network forms, and how it can get unreliable at times, I am not sure I would go that route for such a large building and a critical device like a thermostat. You are most likely going to be very dependent on the repeaters, and the general pairing of the thermostats (which it sounds like you kind of already know). Lots of chances for various other 2.4Ghz devices to come and go and interfere with signals at odd times.